An electrophilic hypervalent iodine reagent for trifluoromethylthiolation X Shao, X Wang, T Yang, L Lu, Q Shen Angew. Chem. Int. Ed 52, 3457-3460, 2013 | 424 | 2013 |
Shelf-stable electrophilic reagents for trifluoromethylthiolation X Shao, C Xu, L Lu, Q Shen Accounts of Chemical Research 48 (5), 1227-1236, 2015 | 394 | 2015 |
Highly selective trifluoromethylation of 1, 3-disubstituted arenes through iridium-catalyzed arene borylation. T Liu, X Shao, Y Wu, Q Shen Angewandte Chemie (International ed. in English) 51 (2), 540-543, 2011 | 210 | 2011 |
Silver‐Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion F Hu, X Shao, D Zhu, L Lu, Q Shen Angewandte Chemie International Edition 53 (24), 6105-6109, 2014 | 180 | 2014 |
Structure–reactivity relationship of trifluoromethanesulfenates: discovery of an electrophilic trifluoromethylthiolating reagent X Shao, C Xu, L Lu, Q Shen The Journal of Organic Chemistry 80 (6), 3012-3021, 2015 | 147 | 2015 |
PhSO2SCF2H: A Shelf‐Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation D Zhu, X Shao, X Hong, L Lu, Q Shen Angewandte Chemie 128 (51), 16039-16043, 2016 | 130 | 2016 |
Enantioselective Synthesis of anti-1,2-Diamines by Cu-Catalyzed Reductive Couplings of Azadienes with Aldimines and Ketimines X Shao, K Li, SJ Malcolmson Journal of the American Chemical Society 140 (23), 7083-7087, 2018 | 96 | 2018 |
2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1, 2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones K Li, X Shao, L Tseng, SJ Malcolmson Journal of the American Chemical Society 140 (2), 598-601, 2018 | 83 | 2018 |
Trifluoromethyl-substituted sulfonium ylide: Rh-catalyzed carbenoid addition to trifluoromethylthioether Y Liu, X Shao, P Zhang, L Lu, Q Shen Organic letters 17 (11), 2752-2755, 2015 | 77 | 2015 |
Copper-catalyzed trifluoromethylthiolation of primary and secondary alkylboronic acids X Shao, T Liu, L Lu, Q Shen Organic letters 16 (18), 4738-4741, 2014 | 66 | 2014 |
Direct trifluoromethylthiolation reactions involving radical processes AL Barthelemy, E Magnier, G Dagousset Synthesis 50 (24), 4765-4776, 2018 | 57 | 2018 |
BrØsted acid-catalyzed electrophilic trifluoromethylthiolation of indoles using thermally stable trifluoromethylthiolating reagent B Ma, X Shao, Q Shen Journal of Fluorine Chemistry 171, 73-77, 2015 | 54 | 2015 |
Recent advances in difluoromethylthiolation X Xiao, ZT Zheng, T Li, JL Zheng, T Tao, LM Chen, JY Gu, X Yao, JH Lin, ... Synthesis 52 (02), 197-207, 2020 | 40 | 2020 |
Enantio-and diastereoselective synthesis of homoallylic α-trifluoromethyl amines by catalytic hydroalkylation of dienes CI Onyeagusi, X Shao, SJ Malcolmson Organic letters 22 (4), 1681-1685, 2020 | 34 | 2020 |
A Diastereodivergent and Enantioselective Approach to syn- and anti-Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines … P Zhou, X Shao, SJ Malcolmson Journal of the American Chemical Society 143 (34), 13999-14008, 2021 | 30 | 2021 |
Construction of diverse C–S/C–Se bonds via nickel catalyzed reductive coupling employing thiosulfonates and a selenosulfonate under mild conditions Y Liu, S Xing, J Zhang, W Liu, Y Xu, Y Zhang, K Yang, L Yang, K Jiang, ... Organic Chemistry Frontiers 9 (5), 1375-1382, 2022 | 25 | 2022 |
Catalytic enantio-and diastereoselective cyclopropanation of 2-azadienes for the synthesis of aminocyclopropanes bearing quaternary carbon stereogenic centers X Shao, SJ Malcolmson Organic letters 21 (18), 7380-7385, 2019 | 20 | 2019 |
Cobalt-catalyzed hydro-difluoromethylthiolation/hydro-trifluoromethylthiolation of unactivated alkenes X Shao, X Hong, L Lu, Q Shen Tetrahedron 75 (31), 4156-4166, 2019 | 20 | 2019 |
Visible-light-mediated synthesis of trifluoromethylthiolated arenes C Ghiazza, C Monnereau, L Khrouz, T Billard, A Tlili Synthesis 51 (14), 2865-2870, 2019 | 15 | 2019 |
Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer J Zhang, M Jiang, CS Wang, K Guo, QX Li, C Ma, SF Ni, GQ Chen, Y Zong, ... Nature Communications 13 (1), 7961, 2022 | 14 | 2022 |