| Synthetic analogues of cysteinate-ligated non-heme iron and non-corrinoid cobalt enzymes JA Kovacs Chemical reviews 104 (2), 825-848, 2004 | 335 | 2004 |
| Nickel L-Edge Soft X-ray Spectroscopy of Nickel− Iron Hydrogenases and Model Compounds Evidence for High-Spin Nickel (II) in the Active Enzyme H Wang, CY Ralston, DS Patil, RM Jones, W Gu, M Verhagen, M Adams, ... Journal of the American Chemical Society 122 (43), 10544-10552, 2000 | 169 | 2000 |
| Synthetic Models for the Cysteinate-Ligated Non-Heme Iron Enzyme Superoxide Reductase: Observation and Structural Characterization by XAS of an FeIII−OOH … J Shearer, RC Scarrow, JA Kovacs Journal of the American Chemical Society 124 (39), 11709-11717, 2002 | 113 | 2002 |
| How Does Single Oxygen Atom Addition Affect the Properties of an Fe− Nitrile Hydratase Analogue? The Compensatory Role of the Unmodified Thiolate P Lugo-Mas, A Dey, L Xu, SD Davin, J Benedict, W Kaminsky, ... Journal of the American Chemical Society 128 (34), 11211-11221, 2006 | 108 | 2006 |
| Sulfur K-edge XAS and DFT calculations on nitrile hydratase: geometric and electronic structure of the non-heme iron active site A Dey, M Chow, K Taniguchi, P Lugo-Mas, S Davin, M Maeda, JA Kovacs, ... Journal of the American Chemical Society 128 (2), 533-541, 2006 | 106 | 2006 |
| Understanding how the thiolate sulfur contributes to the function of the non-heme iron enzyme superoxide reductase JA Kovacs, LM Brines Accounts of chemical research 40 (7), 501-509, 2007 | 103 | 2007 |
| Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants JA Kovacs, RH Holm Journal of the American Chemical Society 108 (2), 340-341, 1986 | 103 | 1986 |
| Heterometallic clusters: synthesis and reactions of vanadium-iron-sulfur single-and double-cubane clusters and the structure of [V2Fe6S8Cl4 (C2H4S2) 2] 4 JA Kovacs, RH Holm Inorganic Chemistry 26 (5), 702-711, 1987 | 96 | 1987 |
| Characterization of metastable intermediates formed in the reaction between a Mn (II) complex and dioxygen, including a crystallographic structure of a binuclear Mn (III … MK Coggins, X Sun, Y Kwak, EI Solomon, E Rybak-Akimova, JA Kovacs Journal of the American Chemical Society 135 (15), 5631-5640, 2013 | 91 | 2013 |
| Comparative electronic structures of nitrogenase FeMoco and FeVco JA Rees, R Bjornsson, JK Kowalska, FA Lima, J Schlesier, D Sippel, ... Dalton Transactions 46 (8), 2445-2455, 2017 | 87 | 2017 |
| How iron activates O2 JA Kovacs Science 299 (5609), 1024-1025, 2003 | 87 | 2003 |
| How do oxidized thiolate ligands affect the electronic and reactivity properties of a nitrile hydratase model compound? I Kung, D Schweitzer, J Shearer, WD Taylor, HL Jackson, S Lovell, ... Journal of the American Chemical Society 122 (34), 8299-8300, 2000 | 85 | 2000 |
| A functional model for the cysteinate-ligated non-heme iron enzyme superoxide reductase (SOR) T Kitagawa, A Dey, P Lugo-Mas, JB Benedict, W Kaminsky, E Solomon, ... Journal of the American Chemical Society 128 (45), 14448-14449, 2006 | 79 | 2006 |
| Reactivity of five-coordinate models for the thiolate-ligated Fe site of nitrile hydratase JJ Ellison, A Nienstedt, SC Shoner, D Barnhart, JA Cowen, JA Kovacs Journal of the American Chemical Society 120 (23), 5691-5700, 1998 | 74 | 1998 |
| A model for the low-spin, non-heme, thiolate-ligated iron site of nitrile hydratase SC Shoner, D Barnhart, JA Kovacs Inorganic Chemistry 34 (18), 4517-4518, 1995 | 72 | 1995 |
| Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] 2+ core JA Kovacs, RH Holm Inorganic Chemistry 26 (5), 711-718, 1987 | 72 | 1987 |
| Why is there an “inert” metal center in the active site of nitrile hydratase? Reactivity and ligand dissociation from a five-coordinate Co (III) nitrile hydratase model J Shearer, IY Kung, S Lovell, W Kaminsky, JA Kovacs Journal of the American Chemical Society 123 (3), 463-468, 2001 | 71 | 2001 |
| Comparative electronic properties of vanadium-iron-sulfur and molybdenum-iron-sulfur clusters containing isoelectronic cubane-type [VFe3S4] 2+ and [MoFe3S4] 3+ cores MJ Carney, JA Kovacs, YP Zhang, GC Papaefthymiou, K Spartalian, ... Inorganic Chemistry 26 (5), 719-724, 1987 | 68 | 1987 |
| Correlation Between Structural, Spectroscopic, and Reactivity Properties Within a Series of Structurally Analogous Metastable Manganese (III)–Alkylperoxo Complexes MK Coggins, V Martin-Diaconescu, S DeBeer, JA Kovacs Journal of the American Chemical Society 135 (11), 4260-4272, 2013 | 67 | 2013 |
| Structural and Spectroscopic Characterization of Metastable Thiolate-Ligated Manganese (III)–Alkylperoxo Species MK Coggins, JA Kovacs Journal of the American Chemical Society 133 (32), 12470-12473, 2011 | 63 | 2011 |
Jason ShearerSemmes Distinguished Professor of Chemistry, Trinity UniversityVerified email at trinity.edu
